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不同黏粒含量土的固结和重金属吸附解吸特性研究

武亚军1(), 岳皓凡1, 臧学轲2, 张旭东1, 章长松2, 吴金红2   

  1. 1.上海大学 力学与工程科学学院,上海 200444
    2.上海亚新城市建设有限公司,上海 200436
  • 收稿日期:2024-03-11 修回日期:2024-06-05 出版日期:2024-06-19
  • 作者简介:武亚军(1973―),男,山西太谷人,教授,博士生导师,主要从事软土地基与废弃泥处理、土壤修复等方面的教学与研究工作。E-mail: wyjdldz@shu.edu.cn
  • 基金资助:
    国家自然科学基金(42272320);国家自然科学基金(42207168);上海市科技创新行动计划国际合作项目(22230730900);上海市科技创新行动计划国际合作项目(23230713900)

Study on the consolidation and heavy metal adsorption-desorption characteristics of soils with different clay content

WU Ya-jun1(), YUE Hao-fan1, ZANG Xue-ke2, ZHANG Xu-dong1, ZHANG Chang-song2, WU Jin-hong2   

  1. 1. School of Mechanics and Engineering Science, Shanghai University, Shanghai 200444, China
    2. Shanghai Yaxin Urban Construction Co., Ltd, Shanghai 200436, China
  • Received:2024-03-11 Revised:2024-06-05 Published:2024-06-19

摘要:

在实际修复工程中,对高黏粒含量的重金属污染土进行淋洗是十分困难的,这即是因为高黏粒含量土渗透性差,也是因为黏粒含量对于污染土淋洗的具体影响规律和机理尚未明晰。因此,本研究通过固结试验和振荡离心试验探究了不同黏粒含量土壤的固结和重金属吸附解吸特性。研究结果显示,不同黏粒含量土壤的物理力学特性存在显著差别,高黏粒含量土壤具有更高的液塑限和更大的压缩性,而土壤的渗透性和孔隙比则更低。并且,黏粒含量的增加显著提高了土壤对重金属离子的吸附能力,同时降低了药剂淋洗的去除效果。黏粒含量从20%增加到50%,重金属吸附量最大可提高50%,去除率最大可降低20%,其中,在20%和30%黏粒含量之间的变化尤为显著,主要原因是大量团聚体的形成。这些物理力学特性和吸附解吸特性的差别将对土壤淋洗中技术和参数的选择产生较大影响,因此,该试验结论可为重金属污染土淋洗修复技术的优化提供一定的参考依据。

关键词: 重金属污染, 黏粒含量, 沉降法, 固结试验, 吸附-解吸

Abstract:

In practical remediation projects, it is very difficult to leach heavy metal contaminated soil with high clay content. This is not only because high clay content soil has poor permeability, but also because the specific impact and mechanism of clay content on the leaching of contaminated soil are not yet clear. Therefore, this study investigated the consolidation and heavy metal adsorption and desorption characteristics of soils with different clay content through consolidation tests and oscillatory centrifugation tests. The research results show that there are significant differences in the physical and mechanical properties of soils with different clay content. High clay content soils have higher liquid plastic limits and greater compressibility, while soil permeability and porosity are lower. Moreover, the increase in clay content significantly enhances the soil's adsorption capacity for heavy metal ions, while reducing the removal efficiency of chemical leaching. The content of clay particles increases from 20% to 50%, and the maximum adsorption capacity of heavy metals can be increased by 50%, while the removal rate can be reduced by up to 20%. Among them, the change between the clay particle content of 20% and 30% is particularly significant, mainly due to the formation of a large number of aggregates. The differences in these physical and mechanical properties and adsorption desorption characteristics will have a significant impact on the selection of technology and parameters in soil leaching. Therefore, the conclusion of this experiment can provide a certain reference basis for the optimization of heavy metal contaminated soil leaching and remediation technology.

Key words: heavy metal pollution, clay content, sedimentation method, consolidation test, adsorption-desorption

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